Porosimetry Analysis by Mercury Intrusion

Posted July 30, 2010

Mercury intrusion porosimetry involves placing the sample in a special sample cup (penetrometer), then surrounding the sample with mercury. Mercury is a non-wetting liquid to most materials and resists entering voids, doing so only when pressure is applied. The pressure at which mercury enters a pore is inversely proportional to the size of the opening to the void. As mercury is forced to enter pores within the sample material, it is depleted from a capillary stem resevoir connected to the sample cup. The incremental volume depleted after each pressure change is determined by measuring the change in capacitance of the stem. This intrusion volume is recorded with the corresponding pressure or pore size. Mercury porosimetry is applicable to pores from 30 Angstroms up to 900 micrometers in diameter.

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